Diamond cubic Sn-rich nanocrystals: synthesis, microstructure and optical properties

نویسنده

  • Thomas J. Watson
چکیده

Diamond cubic Sn-rich nanocrystals were fabricated with radii less than 20 nm by post-growth annealing at T = 750 ◦C of SnxGe1−x alloys grown on Ge(001) by molecular beam epitaxy. The crystal phase of the Sn-rich nanocrystals was determined to be diamond cubic from Fourier transform analysis of high-resolution transmission electron microscopy images. Optical transmittance of these SnxGe1−x/Ge (001) films demonstrated changes in optical absorption that can be attributed to absorption from the nanocrystals. The energy bandgap was measured to be 0.45 eV for nanocrystals arrays in Ge with a mean diameter of 32 nm. PACS 68.37.Lp; 78.67.Hc; 81.07.Ta; 81.16.Dn; 68.65.Hb

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Colloidal synthesis of germanium nanocrystals

In this study, colloidal germanium nanocrystals were synthesized by a simple and novel method, and their optical properties were also studied. Polyvinyl alcohol (PVA) as a surface modifier was used to control the optical properties of colloidal Ge nanocrystals. Fourier transform infrared spectroscopy (FTIR) analysis was performed to identify the various functional groups present in the sample. ...

متن کامل

Microstructure, mechanical and thermal properties of chalcogenide glasses and glass-ceramics based on Se-As-Ge system nucleated by Sn

In particular, chalcogenide glasses and glass-ceramics are new materials that exhibit good transparency in infrared region (0.8-12µm). We can overcome the main weakness of these glasses by improving the hardness through controlling crystallization. In this paper, we report results of a study on chalcogenide glasses in the ternary system of As-Se-Ge with nominal composition of Snx (Se...

متن کامل

Bi-functional NaLuF4:Gd3+/Yb3+/Er3+ nanocrystals: hydrothermal synthesis, optical and magnetic properties

Magnetic-fluorescent lanthanide doped sodium lutetium fluoride (NaLuF4:Yb3+/Er3+/Gd3+) nanocrystals were synthesized via facile hydrothermal method by varying concentration of Gd3+. Powder X-ray powder diffraction (PXRD), scanning electron microscopy (SEM),transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), p...

متن کامل

New Method for Synthesis of Zinc Metaborate Zn4B6O13 Crystals via Sol-Gel Process and Investigation of DFT Calculations

In this work facile sol-gel (pechni) method has been successfully established to synthesize Zn4B6O13 nanocrystals which have cubic crystals with lattice parameter: a =7.48 A. The structure and morphology of the obtained material were studied by X-ray diffraction (XRD), Infrared spectra (IR), scanning electron microscopy (SEM) and photoluminescence analysis. The experimental results show a band ...

متن کامل

New Method for Synthesis of Zinc Metaborate Zn4B6O13 Crystals via Sol-Gel Process and Investigation of DFT Calculations

In this work facile sol-gel (pechni) method has been successfully established to synthesize Zn4B6O13 nanocrystals which have cubic crystals with lattice parameter: a =7.48 A. The structure and morphology of the obtained material were studied by X-ray diffraction (XRD), Infrared spectra (IR), scanning electron microscopy (SEM) and photoluminescence analysis. The experimental results show a band ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2005